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51.
Seasonal variations of the spectra of wind speed and air temperature in the mesoscale frequency range from 1.3 × 10-4 to 1.5 × 10-3 Hz (10 min to 2 h periods) have been studied through observations over land for one year. Spectrographs [time series of isopleths of spectral densities, f · S(f) vs f] of wind speed and air temperature contain occasional peaks that are attributed to short-lived mesoscale atmospheric activity with narrow frequency bands. Significant spectral peaks of wind speed were found in 19% of the total observations in winter, and in 15–16% in the other seasons; for air temperature, they occured in 12% of observations in autumn, and in 16–19% in the other seasons. The peaks most often occurred in the period range from 30 min to 1 h; most had durations less than 24 h. Mesoscale fluctuations of wind speed and air temperature were highly correlated, and in most cases, phase differences were 90–180 ° with air temperature leading wind speed. Significant spectral peaks of wind speed often occurred during northerly seasonal cold winds in winter, and accompanied tropical and/or mid-latitude cyclones in the other seasons. When the peaks occurred, wind speed was usually relatively high and the atmospheric surface layer was unstable.  相似文献   
52.
The objective of this paper is to propose an FFT technique symmetrical for time and frequency, in which the symmetrization is done by introducing generating functions. By the symmetrical treatment, it becomes possible to derive several complementary relations in the time and frequency domains. Based on the idea of the symmetrical FFT technique, the phase problem of seismic waves is discussed not only in the frequency domain but also in the time domain. Furthermore, the deconvolution technique to evaluate the minimum-phase-shift and all-pass functions of seismic waves, which is not discussed sufficiently in earthquake engineering, is developed in the two domains. Numerical examples to present these basic ideas are also illustrated in the symmetrical framework.  相似文献   
53.
We report on the petrology, mineralogic properties and contents of major elements and trace elements Ag, Au, Bi, Cd, Co, Cs, Ga, In, Rb, Se, Te, Tl, U and Zn (determined by radiochemical neutron activation analysis) in Yamato 74160, interpreted as an LL7 chondrite. All properties are consistent with this meteorite having been recrystallized and partially melted locally once at temperatures well above 1090°C under conditions such that some minerals (e.g. plagioclase, euhedral pyroxene, tetrataenite) grew from melt pockets and siderophilic and chalcophilic elements were lost by extraction into eutectic melt that drained away. Inhomogeneous plagioclase compositions and mobile element loss suggest shock as the most likely heat source. Yamato 74160, while inferentially chondritic, is a larval achondrite: even higher temperatures and longer times would have been required to cause the separations necessary to transform it to an identifiable achondrite type.  相似文献   
54.
Three dimensional P-wave velocity structure beneath the Tohoku district, northeastern Japan arc, is investigated by an inversion of arrival times from local earthquakes using the method originally due to Aki and Lee (1976).In the crust (0–32 km depth) a low-velocity region is found along the volcanic front and its vicinity. Velocities at depths of 32–65 km are low beneath the regions where many Quaternary volcanoes and geothermal areas are distributed. In the region deeper than 65 km, the subduction of the Pacific plate is clearly revealed, and the mantle structure above the descending plate is rather uniform. These features suggest that volcanic activities have relation to the upper mantle structure. The results obtained in this study will be helpful in investigating the mechanism of magma generation in a subduction zone.  相似文献   
55.
Néel temperature (Tm N of α-Fe2SiO4 (fayalite) was measured as a function of pressure by means of Mössbauer spectroscopy in the pressure range 0–16 Gpa. High pressure was generated using a clamp-type miniature diamond anvil cell which was inserted into a cryostat. The Néel temperature increased linearly with increasing pressure at a rate of dT N /dp=2.2±0.2 K/GPa. The result is discussed on the basis of the model proposed for the magnetic structure of fayalite by Santoro et al. (1966). The observed dT N /dp suggests that the superexchange interactions vary as the ?10/3 power of the volume while the volume dependence of the direct exchange interactions is positive and small.  相似文献   
56.
The rates of chemical reactions between aqueous sulfates and sulfides are essentially identical to sulfur isotopic exchange rates between them, because both the chemical and isotopic reactions involve simultaneous oxidation of sulfide-sulfur atoms and reduction of sulfate-sulfur. The rate of reaction can be expressed as a second order rate law: R = k·[∑SO42?]·[∑S2?], where R is the overall rate, k is the rate constant and [∑SO42?] and [∑S2?] are molal concentrations. We have computed the rate constants from the available experimental data on the partial exchange of sulfur isotopes between aqueous sulfates and sulfides using the rate law established by us: ln(αe ? ααe ? α0) = ? kt([∑SO42?] + [∑S2?]), where t is time and α0, α, and αe are, respectively, the fractionation factors at t = 0 (the initial condition), at the end of experiment, and at equilibrium. The equilibrium fractionation factor can be expressed as: 1000 ln αe = 6.463 × 106T2 + 0.56 (±.5) (T in Kelvin).The rate constants are strongly dependent on T and pH, but not in as simple a manner as suggested by Igumnov (1976). Our rate constants in Na-bearing hydrothermal solutions decrease by 1 order of magnitude with an increase in pH by 1 unit at pH's less than ~3, remain constant in the pH range of ~4 to ~7, and again decrease at pH >7. The activation energy for the reaction also depends on pH: 18.4 ± 1 kcal/mole at pH = 2, 29.6 ± 1 kcal/mole at pH = 4 to 7, and between 40 and 47 kcal/mole at pH around 9. The observed pH dependence of the rate constant and of the activation energy can be best explained by a model involving thiosulfate molecules as reaction intermediates, in which the intramolecular exchange of sulfur atoms in thiosulfates becomes the rate determining step.The rate constants obtained in this study were used to compute the changes in the isotopic fractionation factors between aqueous sulfates and sulfides during cooling of fluids. Comparisons with data of coexisting sulfate-sulfide minerals in hydrothermal deposits, suggest that simple cooling was not a likely mechanism for coprecipitation of sulfate and sulfide minerals at temperatures below 350°C. Mixing of sulfide-rich solutions with sulfate-rich solutions at or near the depositional sites is a more reasonable process for explaining the observed fractionation.The degree of attainment of chemical equilibrium between aqueous sulfates and sulfides in a hydrothermal system, and the applicability of aO2-pH type diagrams to mineral deposits, depends on the ∑S content and the thermal history of the fluid, which in turn is controlled by the flow rate and the thermal gradient in the system.The rates of sulfate reduction by non-bacterial processes involving a variety of reductants are also dependent on T, pH, [∑SO42?], and [∑S2?], and appear to be fast enough to become geochemically important at temperatures above about 200°C.  相似文献   
57.
The Eoarchaean (>3,600 Ma) Itsaq Gneiss Complex of southern West Greenland is dominated by polyphase orthogneisses with a complex Archaean tectonothermal history. Some of the orthogneisses have c. 3,850 Ma zircons, and they vary from rare single phase metatonalites to more common complexly banded migmatites. This is due to heterogeneous strain, in situ anatexis and granitic veining superimposed during younger tectonothermal events. In the single-phase tonalites with c. 3,850 Ma zircon, oscillatory-zoned prismatic zircon is all 3,850 Ma old, but shows patchy ancient loss of radiogenic Pb. SHRIMP spot analyses and laser ablation ICP-MS depth profiling show that thin (usually < 10 μm) younger (3,660–3,590 Ma and Neoarchaean) shells of lower Th/U metamorphic zircon are present on these 3,850 Ma zircons. Several samples with this simple zircon population occur on islands near Akilia. In contrast, migmatites usually contain more complex zircon populations, with often more than one generation of igneous zircon present. Additional zircon dating of banded gneisses across the Complex shows that samples with c. 3,850 Ma igneous zircon are not just a phenomenon restricted to Akilia and adjacent islands. For example, migmatites from Itilleq (c. 65 km from Akilia) contain variable amounts of oscillatory-zoned 3,850 Ma and 3,650 Ma zircon, interpreted, respectively, as the rock age and the time of crustal melting under Eoarchaean metamorphism. With only 110–140 ppm Zr in the tonalites and likely magmatic temperatures of >850°C, zircon solubility–melt composition relationships show that they were only one-third saturated in zircon. Any zircon entrained in the precursor magmas would thus have been highly soluble. Combined with the cathodoluminesence imaging, this demonstrates that the c. 3,850 Ma oscillatory zoned zircon crystallised out of the melt and hence gives a magmatic age. Thus the rare well-preserved tonalites and palaeosome in migmatites testify that c. 3,850 Ma quartzo–feldspathic rocks are a widespread (but probably minor) component in the Itsaq Gneiss Complex. C. 3,850 Ma zircon with negative Eu anomalies (showing growth in felsic systems) also occurs as detrital grains in rare c. 3,800 Ma metaquartzites and as inherited grains in some 3,660 Ma granites (sensu stricto). These demonstrate that still more c. 3,850 Ma rocks were present, but were recycled into Eoarchaean sediments and crustally derived granites. The major and trace element characteristics (e.g. LREE enrichment, HREE depletion, low MgO) of the best-preserved c. 3,850 Ma rocks are typical of Archaean TTG suites, and thus argue for crust formation processes involving important contributions from melting of hydrated mafic crust to the earliest Archaean. Five c. 3,850 Ma tonalites were selected as the best preserved on the basis of field criteria and zircon petrology. Four of these samples have overlapping initial ɛNd (3,850 Ma) values from +2.9 to +3.6± 0.5, with the fourth having a slightly lower value of +0.6. These data provide additional evidence for a markedly LREE-depleted early terrestrial mantle reservoir. The role of c. 3,850 Ma crust should be considered in interpreting isotope signatures of the younger (3,800–3,600 Ma) rocks of the Itsaq Gneiss Complex. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   
58.
Seismic wave energy in surface layers is calculated based on vertical array records at four sites during the 1995 Hyogo-ken Nambu earthquake by assuming vertical propagation of SH waves. The upward energy generally tends to decrease as it goes up from the base layer to the ground surface particularly in soft soil sites. Theoretical study on 1D multi-layers model to investigate the basic energy flow mechanism indicates that the energy at the ground surface can be smaller on softer soils due to high soil damping during strong shaking even if resonance effect is considered. A simple calculation for a shear-vibrating structure resting on foundation ground shows that induced strain in the structure is directly related to the energy or the energy flux of surface layers. Hence, a general perception that soft soil sites tend to suffer heavier damage than stiff sites should be explained not by greater incident energy but by other reasons such as degree of resonance. Furthermore, it is recommended that not only acceleration or velocity but also S-wave velocity should be specified at a layer where a design seismic motion is given, so that the seismic wave energy can clearly be quantified in seismic design practice.  相似文献   
59.
A new coastal marine ecosystem model was developed, which was composed of pelagic and benthic ecosystems, and was applied to Mikawa Bay, Japan. This model deals with variations of biochemical and physical interactions among dissolved oxygen and C–N–P species (composition formed out of carbon, nitrogen and phosphorus elements) so that it resolves the flux dynamics of carbon, nitrogen, phosphorus and oxygen elements. The physical and biochemical mechanism figured in this model is constructed for the purpose of simulating the estuarine lower trophic ecosystem, in areas where the sea was too deep for light to reach the sea-bottom. As a result of coupling the benthic with pelagic system, the effect of process of sedimentation and nutrient diffusion back to the pelagic system could be indicated. In addition, by implementing the tidal flat ecosystem model's calculation result, the integrated model can include the effect of water purification in tidal flats where the light can reach the sea-bottom, and where sea-weed, sea grass and benthic algae exist. In this study, the model indicates that oxygen-depleted water exists at the sea-bottom especially in summer mainly caused by an increase of oxygen consumption in the benthic system and a decrease of the vertical mixing water process. Furthermore, by comparing the case – with the tidal flat ecosystem model and the case without it, the effect of water purification of tidal flat estuaries was indicated. From the viewpoint of a short time scale, the tidal flat has the potential to restrict red tide (rapid increase of phytoplankton), and from the viewpoint of a long time scale, it restricts the sedimentation of detritus. Restricting the sedimentation prevents oxygen-depleted water occurring in the coastal marine system of Mikawa Bay.  相似文献   
60.
Abstract In order to make geophysical and geological investigations of the Nojima Fault on Awaji Island, Japan, three boreholes measuring 1800 m, 800 m and 500 m deep were drilled into the fault zone. The fault is one of the seismic source faults of the 1995 Hyogo-ken Nanbu earthquake of M 7.2. A new multicomponent borehole instrument was installed at the bottom of the 800 m borehole and continuous observations of crustal strain and tilt have been made using this instrument since May 1996. A high-pressure water injection experiment within the 1800 m borehole was done in February and March 1997 to study the geophysical response, behavior, permeability, and other aspects of the fault zone. The injection site was located approximately 140 m horizontally and 800 m vertically from the instrument. Associated with the water injection, contraction of approximately 0.7 × 10−7 str (almost parallel to the fault) and tilt of approximately 1 × 10-7 rad in the sense of upheaval toward the injection site were observed. In addition to these controlled experiments, the strainmeter and tiltmeter also recorded daily variations. We interpret strain and tilt changes to be related to groundwater discharge and increased ultra-micro seismicity induced by the injected water.  相似文献   
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